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JOURNALS // Optics and Spectroscopy // Archive

Optics and Spectroscopy, 2020 Volume 128, Issue 5, Pages 603–606 (Mi os413)

This article is cited in 8 papers

Spectroscopy of condensed matter

Hydrogen influence on the optical transparency of palladium layers

V. A. Shutaeva, E. A. Grebenshchikovaa, V. G. Sidorovb, Yu. P. Yakovleva

a Ioffe Institute, St. Petersburg
b IBSG Co., Ltd., St.Petersburg

Abstract: The optical transparency of palladium layers within the wavelength region from 0.5 to 1.1 $\mu$m in air and in gaseous mixtures containing hydrogen in the range of 0.1 to 100 vol.% has been studied. The thermal-vacuum deposition method was used to prepare palladium layers on glass substrate. Buger's law is implemented for layers thickness of order 450 $\mathring{\mathrm{A}}$. Pd layers of more than 1200 $\mathring{\mathrm{A}}$ are damaged in 100% hydrogen medium. At some hydrogen concentration between 1–10 vol.% a sharp increase in Pd layer transparency is observed that is intrinsic for the first-order phase transition. The layer transparency change speed increases linearly with increasing the hydrogen concentration in gas medium.

Keywords: palladium, hydrogen, optical transparency, phase transition.

Received: 26.09.2019
Revised: 30.01.2020
Accepted: 03.02.2020

DOI: 10.21883/OS.2020.05.49316.276-19


 English version:
Optics and Spectroscopy, 2020, 128:5, 596–599

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© Steklov Math. Inst. of RAS, 2026