This article is cited in 2 papers

Spectroscopy of condensed matter

The influence of the nature of halogen on the local structure and intercalation of water in oxyhalides Ba$_{2}$InO$_{3}$X (X = F, Cl, Br)

N. A. Tarasova, I. E. Animitsa

First President of Russia Boris Yeltsin Ural Federal University, Yekaterinburg, 620002, Russia

Abstract: Oxyhalides Ba$_{2}$InO$_{3}$F, Ba$_{2}$InO$_{3}$Cl, and Ba$_{2}$InO$_{3}$Br, are synthesized, and their phase homogeneity is confirmed by the method of X-ray diffraction. The influence of the nature of a halide ion on the crystal-lattice parameters and on the In–O bond lengths is established. The ability of the studied phases to undergo hydration and formation of oxygen–hydrogen groups in their structure is proven.

Received: 27.07.2017

DOI: 10.21883/OS.2018.02.45518.171-17

 English version: Optics and Spectroscopy, 2018, 124:2, 163–166

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