This article is cited in 8 papers

Communications

Solvent-free palladium-catalyzed C–O cross-coupling of aryl bromides with phenols

S. A. Rzhevskiy^ab, M. A. Topchiy^ab, V. N. Bogachev^a, L. I. Minaeva^a, I. R. Cherkashchenko^ab, K. V. Lavrov^c, G. K. Sterligov^a, M. S. Nechaev^ab, A. F. Asachenko<sup>ab

a</sup> A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^c National Research Centre 'Kurchatov Institute', Moscow, Russian Federation

Abstract: A new solvent-free procedure for C–O cross-coupling between phenols and aryl bromides comprising of Pd₂(dba)₃/Bu^tBrettPhos catalytic system is efficient for substrates bearing donor or acceptor, as well as bulky substituents.

Keywords: cross-coupling, phenols, arylation, solvent-free reactions, Pd-catalysis, aryl bromides, diaryl ethers.

Language: English

DOI: 10.1016/j.mencom.2021.04.042

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