This article is cited in 2 papers

Communications

Synthesis of B-silylmethyl substituted o- and m-carboranes

B. A. Izmaylov, V. A. Vasnev, G. D. Markova

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Monosubstituted B-chloro(organyl)silylmethyl-o- and m-carboranes have been synthesized by the reaction of o(m)-carboranes with chloro(chloromethyl)organylsilanes in the presence of AlCl₃ at 200–250°C under a pressure of 20–25atm.

Keywords: o(m)-carborane, chloro(chloromethyl)organylsilanes, B-chloro(organo)silyl-o(m)-carboranes, Fridel–Crafts reaction, organosilicon compounds.

Language: English

DOI: 10.1016/j.mencom.2021.01.042

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