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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2022 Volume 32, Issue 5, Pages 645–648 (Mi mendc754)

This article is cited in 6 papers

Communications

Tracking nitrogen-to-nickel ratio and prevalent paramagnetic species in synthetic diamonds by electron spin resonance at 90 K

V. Yu. Osipova, F. M. Shakhova, N. M. Romanovbc, K. Takaid

a Ioffe Institute, St. Petersburg, Russian Federation
b Peter the Great St. Petersburg Polytechnic University, St. Petersburg, Russian Federation
c Joint-Stock Company 'Svetlana-Semiconductors', St. Petersburg, Russian Federation
d Department of Chemical Science and Technology, Hosei University, Tokyo, Japan

Abstract: Nitrogen and nickel are the main impurities in the type Ib synthetic diamonds obtained under high pressure and high temperature conditions using nickel-containing catalysts. Nitrogen enters the synthesized diamond from the air. The nickel/nitrogen ratio for the two types of diamonds, obtained with and without an aluminum getter that prevents the diamond crystal lattice from nitrogen penetration, was studied by electron spin resonance at 90 K.

Keywords: synthetic diamond, impurities, high pressure and high temperature, electron spin resonance, solid state chemistry, analytical chemistry.

Language: English

DOI: 10.1016/j.mencom.2022.09.026



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