Communications

Hydrogenation of diverse substrates over covalent triazine framework modified with copper

E. V. Shuvalova^a, V. N. Zakharov^b, V. V. Chernyshev^b, L. A. Aslanov^b, L. M. Kustov<sup>ab

a</sup> N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
^b Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation

Abstract: Triazine-based covalent organic framework CTF-1 was prepared via polymerization of 1,4-dicyanobenzene catalyzed by zinc chloride followed by the post-synthesis treatment of the obtained material using ultrasonication to effectively remove the impurities. The CTF-1 material was further modified by transition metal, namely, copper, and tested as the catalyst for hydrogenation of two alkynes and nitrobenzene.

Keywords: triazine covalent organic frameworks, catalysis, hydrogenation, phenylacetylene, nitrobenzene, but-2-yne-1,4-diol.

Received: 29.04.2025
Accepted: 04.08.2025

Language: English

DOI: 10.71267/mencom.7814

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