This article is cited in 1 paper

Communications

Effect of pH on the reaction outcome between tetraacetyl hexaazaisowurtzitane and aldehydes

D. A. Kulagina, S. V. Sysolyatin

Institute for Problems of Chemical & Energetic Technologies, Siberian Branch of the Russian Academy of Sciences, Biysk, Russian Federation

Abstract: 2,6,8,12-Tetraacetyl-2,4,6,8,10,12-hexaazaisowurtzitane was subjected to N-aminomethylation under various conditions, which afforded new derivatives of aminal nature. The highest yields were achieved when the reactions were carried out in a weak-alkali medium.

Keywords: hexaazaisowurtzitanes, formaldehyde, aldehydes, N-aminomethylation, acetals, aminals, cage compounds.

Language: English

DOI: 10.1016/j.mencom.2022.05.018

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