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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1991 Volume 1, Issue 4, Pages 149–151 (Mi mendc5552)

This article is cited in 4 papers

Unusual Reactions of 2,3,5-Trichloro-4,4-dimethoxy-5-allylcyclopent-2-en-1-one with Amines

S. A. Ismailova, M. S. Miftakhova, G. A. Tolstikovb

a Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: The transformation of enaminochlorovinyl ketone 2 via the diketone 3 into a mixture of keto–enol tautomers 4 and 5, synthons for 13-azaprostanoids, is described; reactions of compound 1 with amine derivatives of different types leading to abnormal products have also been studied.

Language: English

DOI: 10.1070/MC1991v001n04ABEH000091



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