This article is cited in 4 papers

New Chirones Prepared from 2-Acetoxyglucal

A. G. Tolstikov^a, E. E. Savateeva^b, L. V. Spirikhin^b, G. A. Tolstikov<sup>c

a</sup> G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
^c N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: Reaction of 2,3,4,6-tetra-O-acetyl-D-glucal with allyltrimethylsilane, methyl 3-mercaptopropionate, methyl (6R)-6-benzoyloxy-7-oxyheptanoate or glycolic acid methyl ester, catalysed by boron trifluride etherate, leads preferentially to the a-anomers of unsaturated 2’-oxo-C-, S- or O-glycosides.

Language: English

DOI: 10.1070/MC1991v001n04ABEH000082

Bibliographic databases:

•