This article is cited in 47 papers

First Example of the η³-Prop-2-ynyl Ligand; Synthesis and Reactivity of Cationic (η³-Prop-2-ynyl)arenedicarbonylmolybdenum Complexes; X-Ray Structure of [Mo(CO)2(η6-C6Me5H)(η3-HCCCH2)]+BF4−

V. V. Krivykh, E. S. Taits, P. V. Petrovskii, Yu. T. Struchkov, A. I. Yanovsky

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A series of (η³-prop-2-ynyl)arenedicarbonylmolybdenum complexes with a novel η³-prop-2-ynyl ligand have been obtained, their structure has been established unambiguously by an X-ray diffraction study of a pentamethylbenzene derivative; the reactions of the η3-prop-2-ynyl derivatives with H₂O and PPh₃ yield complexes with 2-hydroxyallyl, 2-triphenyl phosphonioallyl and 1-triphenylphosphoionallene ligands.

Language: English

DOI: 10.1070/MC1991v001n03ABEH000063

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