This article is cited in 14 papers

Unexpected Oxidation of a Coordinated Phosphine Ligand. Synthesis and Molecular Structure of [Pd( μ-O₂PPh₂)(C₆H₅)(PPh₃)]₂

N. Yu. Kozitsyna^a, A. M. Ellern^a, M. Yu. Antipin^b, Yu. T. Struchkov^b, I. I. Moiseev<sup>a

a</sup> N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The reaction of [Pd(OAc)₂(PPh₃)]₂ with HCO₂H includes the transfer of an O atom from the carboxylic ligand to the P atom and cleavage of the P—Ph bond accompanied by transfer of the Ph group from PPh₃ ligand to the palladium atom; the structure of the complex formed, [Pd(μ-O₂PPh₂)(C₆H₅)(PPh₃)]₂, has been resolved by X-ray analysis.

Language: English

DOI: 10.1070/MC1991v001n03ABEH000056

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