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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1991 Volume 1, Issue 3, Pages 83–84 (Mi mendc5511)

This article is cited in 5 papers

3,3-Sigmatropic Shift Mechanism for Circumambulation of Acyloxy Groups around the Cyclopentadiene Ring

I. E. Mikhailova, G. A. Dushenkoa, I. A. Kamenetskayaa, O. E. Kompana, Yu. T. Struchkovb, V. I. Minkina

a Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: 1H NMR spectral data and an X-ray structural analysis of 5-acyloxy-5-benzyl-1,2,3,4-tetraphenylcyclopenta-1,3-diene have elucidated the 3,3-sigmatropic shift pathway of circumambulation of the acyloxy group around the cyclopentadiene ring.

Language: English

DOI: 10.1070/MC1991v001n03ABEH000050



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