Mendeleev Commun., 1991 Volume 1, Issue 2, Page 51
(Mi mendc5490)
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5 papers
Synthesis and Acid-induced Ring Opening of Modified Glycals. Synthons for (14R ,15R )-Lipoxin B and (7S ,8R )-( – )-Disparlure A. G. Tolstikov a ,
O. F. Prokopenko b ,
L. M. Khalilov c ,
L. V. Spirikhin b ,
G. A. Tolstikov d a G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation b Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation c Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation d N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation Abstract:
The chiral 1,2-unsaturated dihydroxyaldehydes
7 and
11 were synthesized as synthons for (14
R ,15
R )-lipoxin B
12 and (7
S ,8
R )-( – )-
cis -disparlure
13 , based on new glycals
6 and
10 prepared from α-
d -galactose.
Language: English
DOI:
10.1070/MC1991v001n02ABEH000029
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