This article is cited in 11 papers

The First Palladium Carbene Cluster: Synthesis and Structure

T. A. Stromnova^a, I. N. Busygina^a, D. I. Kochubey^b, I. I. Moiseev<sup>a

a</sup> N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: The first palladium carbene cluster, μ₂-tetrakis(diphenylmethylidene)-μ₂-tetraacetato-quadro-tetrapalladiurn(4Pd–Pd) Pd₄(μ-CPh₂)₄(μ-OAc)₄, has been obtained by substitution of diphenylcarbene ligands for CO groups in μ₂-tetrakis(carbonyl)-μ₂-tetraacetato-quadro-tetrapalladium(4Pd–Pd) Pd₄(μ-CO)₄(μ-OAc)₄; the cluster is also the first palladium complex containing carbene ligands of the Schrock type.

Language: English

DOI: 10.1070/MC1991v001n01ABEH000001

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