This article is cited in 6 papers

Base Acceleration of Alkane Oxidation by an Iron-porphyrin−Hypochlorite System. Activity, Selectivity and Kinetic Isotope Effect

A. B. Sorokin^a, A. M. Khenkin^a, A. E. Shilov<sup>b

a</sup> Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Addition of alkali strongly accelerates the oxidation of cyciohexane by an iron tetramesitylporphyrin−NaOCl system, the selectivity of the reaction and the H−D kinetic isotope effect also being affected; possible mechanisms of OH⁻ action are discussed

Language: English

DOI: 10.1070/MC1992v002n04ABEH000172

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