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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1992 Volume 2, Issue 3, Pages 118–120 (Mi mendc5436)

This article is cited in 20 papers

The First Structurally Characterized Organolanthanoid Compound with an Anthracene Dianion Ligand. Synthesis and Structure (at 143 K) of η5-(C5H5)LU(C14H10 2−) 2thf (thf = tetrahydrofuran)

D. M. Roitershteina, A. M. Ellernb, M. Yu. Antipinc, L. F. Rybakovaa, Yu. T. Struchkovc, E. S. Petrova

a State Scientific Centre of Russian Federation 'L.Ya. Karpov Institute of Physical Chemistry', Moscow, Russian Federation
b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The interaction of -η5-(C5H5)LuCI2 with Na+2(C14H10 2−) or Na+(C14H1O 2−) has led to the formation of η5-(C5H5)LU(C14H10 2−) -2thf (thf = tetrahydrofuran), containing anthracene dianion as a ligand and the structure of the new complex has been established by a low-temperature X-ray diffraction study at 143 K.

Language: English

DOI: 10.1070/MC1992v002n03ABEH000165



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