This article is cited in 7 papers

Synthesis of 2-Arylcarboxylic Acids and C-Norbenzomorphans via η⁶-Arenetricarbonylchromium Complexes

V. N. Kalinin, I. A. Cherepanov, S. K. Moiseev

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A method for the regioselective carboxylation of (η⁶-alkylarene)tricarbonylchromium complexes at the benzylic position has been developed via the reaction of the corresponding lithium derivatives with carbon dioxide in tetrahydrofuran; a method for the preparation of 5-acetoxy-3-benzyl-1,4-methano-2,3-4,5-tetrahydro-1H-3-benzazepine from 1-tetralol is described.

Language: English

DOI: 10.1070/MC1992v002n03ABEH000161

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