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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1992 Volume 2, Issue 1, Pages 18–19 (Mi mendc5373)

This article is cited in 5 papers

p,π-lnteraction in the Y—C=C Group

V. P. Feshin

Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences, Perm, Russian Federation

Abstract: The electric field gradient asymmetry parameters for 35Cl nuclei in compounds of the series Cl2C=CHOR, Cl2CHOCOR etc. do not corroborate a widespread representation of a p,π-interaction between the unshared electron pair of a Cl atom and the π-electron double bond system in these molecules.

Language: English

DOI: 10.1070/MC1992v002n01ABEH000102



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