This article is cited in 1 paper

Phenazine Di-N-toxide Radical Cation Reactions with Secondary Amines. Evidence for Oxygen Cation Transfer

E. M. Koldasheva^a, Yu. V. Geletii^b, A. F. Shestakov^a, A. V. Kulikov^a, A. E. Shilov<sup>c

a</sup> Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b Department of Chemistry, Texas A and M University, College Station, TX, USA
^c N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A novel reaction involving O⁺ transfer from phenazine di-N-oxide radical cation (OPO^+.) to secondary amines to form phenazine mono-N-oxide (OP) and nitroxyl radical has been observed and investigated by cyclic voltammetry and EPR methods.

Language: English

DOI: 10.1070/MC1993v003n04ABEH000258

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