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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1993 Volume 3, Issue 2, Pages 62–64 (Mi mendc5268)

This article is cited in 5 papers

Calculation of Reaction Rate and Selectivity of Dehydrolinalool Hydrogenation over Pd-Ru Alloy Membrane Catalysts

A. N. Karavanov, I. G. Batirev

A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The calculation of the electron work function and the filling number of the d-band in the bulk and in the first layer, considering the segregation of components in Pd–Ru alloys to be the same as membrane catalysts, has enabled us to explain and calculate the changes in catalyst activity and selectivity in dehydrolinalool hydrogenation with varying Ru content in the alloys.

Language: English

DOI: 10.1070/MC1993v003n02ABEH000225



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