This article is cited in 1 paper

A Short Route to Chiral Synthons: Preparation of Ketoeicosanoids with Hydropyrane Fragments

A. G. Tolstikov^a, E. E. Savateeva^b, N. V. Khakhalina^b, L. V. Spirikhin^b, V. R. Sultanmuratova^b, G. A. Tolstikov<sup>c

a</sup> G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
^c N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: To prepare ketoeicosanoids with hydropyrane fragments, new synthons were obtained from the BF₃·OEt₂ catalysed reaction of tri-O-acetyl-d-glucal with methyl 5-trimethylsilyloxyhex-5-enoate, methyl 10-trimethylsilyloxyundec-10-enoate and the bis(trimethylsilyl)ether of o-hydroxyacetophenone.

Language: English

DOI: 10.1070/MC1993v003n01ABEH000202

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