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Solid-state Chain Photochlorination in Recrystallized Mixtures of Ethene and Chlorine at 30 K

E. Ya. Misochko^a, Ch. A. Wight^b, V. A. Benderskii<sup>a

a</sup> Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b Department of Chemistry, University of Utah, Salt Lake City, Utah, USA

Abstract: Binary solid films of chlorine with ethene have been deposited in excess argon and subsequently recrystaliized by warmingand evaporation of the argon solvent. This novel recrystallization procedure results in a dramatic increase in the quantumyield and degree of conversion for long stereospecific chain photochlorination with the exclusive formation of thefrans-1,2-dichloroethane.

Language: English

DOI: 10.1070/MC1993v003n01ABEH000193

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