This article is cited in 7 papers

Low-energy Barrier to Intramolecular Inversion of Tetrahedral Configuration at a Zn” Centre

V. I. Minkin^a, M. S. Korobov^a, L. E. Nivorozhkin^a, O. E. Kompan^a, R. Ya. Olekhnovich^a, G. S. Borodkin^a, Yu. T. Struchkov<sup>b

a</sup> Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The associative inner-nucleophile assisted mechanism of inversion of tetrahedral configuration at the metal centre in bis-chelate Zn” complexes based on alterdentate ligands, A/-alkylimines of 2,5-diformylpyrrole, has been proved by dynamic ¹H, ¹³C, ¹⁵N NMR spectroscopic and X-ray crystallographic studies.

Language: English

DOI: 10.1070/MC1993v003n01ABEH000192

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