T. S. Kuznetsova, O. V. Eremenko, O. V. Kokoreva, G. V. Zatonsky, N. S. Zefirov, “Synthesis of Cyclo-substituted Triangulanes with Four and Five Spiroannulated Three-membered Rings by Sequential Peripheral Cyclopropanation of Cyclooctene”, Mendeleev Commun., 1994, Volume 4, Issue 5,Page 172

This article is cited in 3 papers

Synthesis of Cyclo-substituted Triangulanes with Four and Five Spiroannulated Three-membered Rings by Sequential Peripheral Cyclopropanation of Cyclooctene

T. S. Kuznetsova^a, O. V. Eremenko^a, O. V. Kokoreva^a, G. V. Zatonsky^b, N. S. Zefirov^a

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Synthesis of pentacyclo[9.1.0.0^{1 3}.0^3.5.0^5.7]dodecane 4 and hexacyclo[10.1.0.0^{1 3}.0^3.5.0^5.7.0^7.9]tridecane 5 has been performed, based on sequential bromocyclopropanation of the C=C bond and elimination to give a repeating endomethylenecyclopropane framework, with termination of the sequence by cyclopropanation.

Language: English

DOI: 10.1070/MC1994v004n05ABEH000399