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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2023 Volume 33, Issue 6, Pages 774–775 (Mi mendc520)

This article is cited in 2 papers

Communications

Synthesis of a new apiol-derived cyclotriveratrylene analog

A. V. Samet, D. V. Tsyganov, V. P. Kislyi, E. I. Tujarov, V. V. Semenov

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: 1,4,6,9,11,14-Hexamethoxy-2,3,7,8,12,13-tris(methylene-dioxy)-10,15-dihydro-5H-tribenzo[a,d,g][9] annulene, a new representative of a cyclotriveratrylene family, was prepared in high yield by acid-catalyzed trimerization of 2,5-di-methoxy-3,4-(methylenedioxy)benzyl alcohol. Structure of the product was confirmed by X-ray diffraction.

Keywords: cyclotriveratrylene, molecular hosts, tribenzo[a,d,g][9]annulenes, apiol, 2,5-dimethoxy-3,4-(methylenedioxy)benzyl alcohol, trimerization.

Language: English

DOI: 10.1016/j.mencom.2023.10.011



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