This article is cited in 1 paper

Communications

1,4-Difluoro-2,5-dimethyl-3,6-bis(diphenylphosphoryl)benzene: Regioselective synthesis and coordination with Mn²⁺ cation

O. I. Artyushin^a, A. G. Matveeva^a, A. V. Vologzhanina^a, P. V. Dorovatovskii^b, V. K. Brel<sup>a

a</sup> A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b National Research Centre 'Kurchatov Institute', Moscow, Russian Federation

Abstract: Regioselective synthesis of 1,4-difluoro-2,5-dimethyl-3,6-bis-(diphenylphosphoryl)benzene from 1,2,4,5-tetraflouro-3,6-dimethylbenzene and preparation of its coordination polymer with Mn²⁺ have been developed. The structures of the ligand and the complex have been determined by X-ray diffraction.

Keywords: 1,4-difluoro-2,5-dimethyl-3,6-bis(diphenylphosphoryl)benzene, phosphines, phosphine oxides, manganese(II) complexes, organofluorine compounds, organophosphorus compounds, X-ray diffraction analysis, NMR spectroscopy.

Language: English

DOI: 10.1016/j.mencom.2023.10.009

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