A. A. Vasil'ev, E. P. Serebryakov, “Catalytic Hydrogenation/Enzymic Hydrolysis as a Route from Alkyl Alka-2,4-dienoates to (<i>Z</i>)-Alk-3-enoic Acids”, Mendeleev Commun., 1994, Volume 4, Issue 1,Pages <nobr>4

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Catalytic Hydrogenation/Enzymic Hydrolysis as a Route from Alkyl Alka-2,4-dienoates to (Z)-Alk-3-enoic Acids

A. A. Vasil'ev, E. P. Serebryakov

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: (Z)-Alk-3-enoic acids of no less than 94% geometrical purity have been obtained from the respective alkyl alka-2,4-dienoates after hydrogenation over chromium hexacarbonyl followed by hydrolysis of the resulting products using porcine pancreatic lipase or KOH in H₂O/MeOH.

Language: English

DOI: 10.1070/MC1994v004n01ABEH000322