This article is cited in 17 papers

A New Catalytic Reaction: Oxidative Carbonylation of Alkynes to Alkynylcarboxylic Acid Esters

T. T. Zung, L. G. Bruk, O. N. Temkin

M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation

Abstract: A new catalytic reaction – oxidative carbonylation of alkynes in the PdCl₂–CuCi system – and the reaction mechanism have been proposed based on the unusual effects of oxygen and copper(i) salts on this process and the key role of σ-alkynylcopper(i) complexes in the reaction.

Language: English

DOI: 10.1070/MC1994v004n01ABEH000321

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