This article is cited in 3 papers

Low Temperature Free Radical Addition Reactions in Solid Argon: F + C₂H₄, an EPR Study

V. A. Benderskii^a, A. U. Goldschleger^a, A. V. Akimov^a, E. Ya. Misochko^a, Ch. A. Wight<sup>b

a</sup> Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b Department of Chemistry, University of Utah, Salt Lake City, Utah, USA

Abstract: Ultraviolet laser photolysis of dilute mixtures of F₂ and C₂H₄ in solid argon form a 2-fluoroethyl radical by addition of translationally ‘hot’ as well as thermal F atoms to ethene; at T > 20 K the major channel is the thermal reaction, which converts up to 25% of ethene to 2-fluoroethyl radical.

Language: English

DOI: 10.1070/MC1995v005n06ABEH000549

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