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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1995 Volume 5, Issue 2, Pages 44–46 (Mi mendc5024)

This article is cited in 3 papers

Metal Complexes of Porphyrin Dimers with Ether and C=C Bonds

E. G. Levinson, N. A. Reztsova, A. F. Mironov

M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation

Abstract: A novel synthesis of a heterometallic complex of ether-bonded porphyrin–chlorin has been performed; metal complexes of α-hydroxyethyl-substituted porphyrins were found to form 2,3-bis-metallporphyrinbut-2-enes in the presence of trifluoroacetic acid; the dimers of two different types exhibited essentially distinct fragmentation in plasma desorption mass spectrometry (PDMS).

Language: English

DOI: 10.1070/MC1995v005n02ABEH000450



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