This article is cited in 6 papers

Photochemical reactions of monomeric and dimeric radical cations of acetone in freon matrices at 77 K

M. Ya. Melnikov, E. N. Seropegina, V. N. Belevskii, S. I. Belopuschkin, D. V. Baskakov

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Monomeric [λ_max ≃ 435 nm, ϵ_max ≃ (3.6 ± 0.6) × l0³ dm³ mol⁻¹ cm⁻¹ ] and dimeric [λ_max ≃ 715 nm, ϵ_max ≃ (9.4 ± 1.2) × l0³ dm³ mol⁻¹ cm⁻¹ ] radical cations of acetone in a freon matrix at 77 K under the action of light react to form matrix radical cations and acetonyl radicals CH₂COMe with quantum yields of Φ > (4.0 ± 1.0) × l0⁻³ and Φ > (2.0 ± 1.0) × l0⁻², respectively.

Language: English

DOI: 10.1070/MC1996v006n05ABEH000636

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