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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1996 Volume 6, Issue 1, Pages 34–36 (Mi mendc4902)

This article is cited in 2 papers

Intermediate paramagnetic centres stabilized in γ-irradiated solid hydrogen cyanide

S. I. Kuzina, P. S. Mozhaev, D. P. Kiryukhin, A. I. Mikhailov, I. M. Barkalov

Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

Abstract: The low temperature radiolysis of HCN gives high yields of the paramagnetic centres C≡N and, mainly, H2C=N radicals which upon subsequent heating to room temperature are shown to polymerise to polyene radicals.

Language: English

DOI: 10.1070/MC1996v006n01ABEH000568



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