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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1997 Volume 7, Issue 5, Pages 198–199 (Mi mendc4854)

This article is cited in 29 papers

The first example of synthesis of aluminacyclopropanes catalysed by (η5-C5H5)2TiCl2

U. M. Dzhemilev, A. G. Ibragimov, L. O. Khafizova, S. V. Rusakov, L. M. Khalilov

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Abstract: The synthesis of a series of cyclic organoaluminium compounds, aluminacyclopropanes, which have never previously been described, has been carried out by α-olefin cyclometallation with EtAlCl2 in the presence of a chlorine ion acceptor, metallic magnesium and Cp2TiCl2 (Cp = η5-C5H5) catalyst.

Language: English

DOI: 10.1070/MC1997v007n05ABEH000791



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