Reactions of chelated Pt^II and Pt^III imidoimino complexes: N-nitrosation involving transfer of an NO group from inorganic nitrites and nitrates

M. O. Ponina, A. A. Sidorov, S. E. Nefedov, I. L. Eremenko, I. I. Moiseev

N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A bis-chelated imidoimino Pt^II complex, [(NPh)(N)C₆H₄]₂Pt 1, was found to undergo N-nitrosation on reacting with AgNO₂ or AgNO₃ to form a product of formal HNO addition, [(NPh)(NNO)C₆H₄][(NPh)(NH)C₆H₄]Pt 3, that was characterised by X-ray analysis; similarly, an amidoimino binuclear Pt^III complex was converted into 3 by reacting with NaNO₂.

Language: English

DOI: 10.1070/MC1998v008n06ABEH001033

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