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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1998 Volume 8, Issue 5, Pages 173–176 (Mi mendc4713)

This article is cited in 13 papers

Kinetic mechanism and chemical oscillations in the branching chain decomposition of nitrogen trichloride

N. M. Rubtsov

A.G. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

Abstract: On the basis of numerical simulation of the branching chain process of the decomposition of nitrogen trichloride it has been shown that suitable conditions for providing oscillating regimes are the following: (a) inclusion of adsorption–desorption of NCl3 on the reactor walls; (b) inclusion of nonlinear chain branching and breaking reactions.

Language: English

DOI: 10.1070/MC1998v008n05ABEH000948



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