This article is cited in 4 papers

Reaction of glycidol with dichloroethers: cyclic and acyclic ortho ester formation

A. A. Bredikhin, S. N. Lazarev

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: The interaction of stoichiometric quantities of glycidol with alkyl dichloromethyl ethers in the presence of 2 equiv. of NEt₃ in diethyl ether leads to formation of diglycidyloxy alkoxy methanes whereas the same reaction involving equimolar quantities of the reagents in benzene in the presence of 1 equiv. of NEt₃ leads to formation of 4-chloromethyl-2-alkoxy-1,3-dioxolanes.

Language: English

DOI: 10.1070/MC1998v008n02ABEH000919

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