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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1999 Volume 9, Issue 4, Page 170 (Mi mendc4580)

This article is cited in 9 papers

Additions and corrections

V. A. Glushkova, Yu. V. Shklyaeva, V. I. Sokolb, V. S. Sergienkob, V. V. Davidovc

a Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences, Perm, Russian Federation
b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
c Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation

Abstract: Earlier described compounds 2b,c as semihydrates of 2,5-cyclohexadien-4-one-spiro-3’-(2’-ethoxycarbonylmethyl-5’,5’-dimethyl-l’pyrroline) (2c) and as 2,5-cyclohexadien-4-one-spiro-3’-(2’-phenyl-5’,5’-dimethyl-l’-pyrroline) (2b), after recording 13C NMR and mass spectra, were found to be ethyl N-[l-(p-hydroxyphenyl)-2-methylpropan-2-yl]malonamate (here 1a) and N-[l-(p-hydroxyphenyl)-2-methylpropan-2-yl]benzamide (here 1b). Named above spiro-compounds 2b,c are formed in the described conditions and can be detected by TLC; however, they are easily converted to amides (here 1a,b) during isolation as a result of hydrolysis in acidic media.

Language: English

DOI: 10.1070/MC1999v009n04ABEH001238



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