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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1999 Volume 9, Issue 4, Pages 144–147 (Mi mendc4567)

This article is cited in 1 paper

Role of electronic factors in the formation of a standard quasi-stable mixture of toxic polychlorinated dibenzo-para-dioxins and polychlorinated dibenzofurans

S. S. Yufit

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Only electronic factors are responsible for the kinetics and mechanism of consecutive chlorination of 2,3,7,8-tetrachlorodibenzo-para-dioxin and 2,3,7,8-tetrachlorodibenzofuran; this results in the formation of a standard quasi-stable mixture of chlorination products (congeners), polychlorinated dibenzo-p-dioxins and dibenzofurans, whose composition was independent of the sample type and the place of sampling.

Language: English

DOI: 10.1070/MC1999v009n04ABEH001072



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