This article is cited in 5 papers

Synthesis of bis(2-tetrahydropyranyl)methanes — new potential precursors for cyclic polyethers

V. V. Samoshin, D. E. Gremyachinskiy, P. H. Gross

Department of Chemistry, University of the Pacific, Stockton, California, USA

Abstract: The TiCl₄- or SnCl₄-promoted cyclization of homoallylic alcohols with malonaldehyde bis(dimethylacetal) affords bis(2-tetrahydropyranyl) methane derivatives, which are potential precursors of C-(1→1)-disaccharides and other cyclic polyethers.

Language: English

DOI: 10.1070/MC1999v009n02ABEH001087

Bibliographic databases:

•