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Mendeleev Commun., 1999 Volume 9, Issue 2, Pages 45–47 (Mi mendc4519)

This article is cited in 3 papers

Structure and conformation of tri-O-acetyl-D-glucal dimer in solid state and in solution

A. H. Franza, V. V. Zhdankinb, V. V. Samoshina, M. J. Mincha, V. G. YoungJrc, P. H. Grossa

a Department of Chemistry, University of the Pacific, Stockton, California, USA
b Department of Chemistry, University of Minnesota Duluth, Duluth, Minnesota, USA
c X-Ray Cristallographic Laboratory, Chemistry Department, University of Minnesota, Minneapolis, Minnesota, USA

Abstract: X-Ray crystallography and 1H NMR spectroscopy indicate that the conformations of both rings A and B and the relative orientation of the rings in the C-linked disaccharide 1,3,4,6-tetra-O-acetyl-2-C-(4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2- enopyranosyl)-2-deoxy-β-D-glucopyranose in solution are virtually identical to the crystalline structure.

Language: English

DOI: 10.1070/MC1999v009n02ABEH001061



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