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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2000 Volume 10, Issue 5, Pages 171–173 (Mi mendc4441)

This article is cited in 12 papers

Aromatic stabilization of organochalcogen compounds with the intramolecular X←O (X = S, Se, Te) coordination

V. I. Minkin, R. M. Minyaev

Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation

Abstract: The ab initio MP2/LanL2DZ calculations predict a significant contribution of cyclic π-electron delocalization to the stabilization of the trans–cis–cis conformation of derivatives of β-chalcogenovinylaldehydes 1 with the intramolecular Chalc←O coordination.

Language: English

DOI: 10.1070/MC2000v010n05ABEH001349



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