This article is cited in 1 paper

Communications

Synthesis of diamantane from new polycyclic hydrocarbons C₁₄ under the action of ionic liquids

R. I. Aminov

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Abstract: Diamantane was obtained by skeletal rearrangement of three new polycyclic hydrocarbons C₁₄H₁₈, C₁₄H₂₀ and C₁₄H₂₂ under the action of aluminate ionic liquids. For the successful isomerization of hydrocarbon C₁₄H₂₂ containing two hydrogen atoms more, the addition of Pd/C to the reaction medium is necessary.

Keywords: polycyclic hydrocarbons, isomerization, diamantane, cyclopropanation, ionic liquids.

Language: English

DOI: 10.1016/j.mencom.2023.06.022

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