Mendeleev Commun., 2000 Volume 10, Issue 3, Pages 88–90
(Mi mendc4398)
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32 papers
The nature of the intramolecular transannular Si···N interaction in crystalline 1-methylsilatrane, as found from X-ray diffraction data
K. A. Lyssenko a ,
A. A. Korlyukov a ,
M. Yu. Antipin a ,
S. P. Knyazev b ,
V. N. Kirin b ,
N. V. Alexeev b ,
E. A. Chernyshev b a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
b M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation
Abstract:
The primarily electrostatic nature of the intramolecular transannular
Si ⋯ N interaction was found from the electron-density distribution in crystalline 1-methylsilatrane at 100 K.
Language: English
DOI:
10.1070/MC2000v010n03ABEH001270
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