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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2000 Volume 10, Issue 3, Pages 88–90 (Mi mendc4398)

This article is cited in 32 papers

The nature of the intramolecular transannular Si···N interaction in crystalline 1-methylsilatrane, as found from X-ray diffraction data

K. A. Lyssenkoa, A. A. Korlyukova, M. Yu. Antipina, S. P. Knyazevb, V. N. Kirinb, N. V. Alexeevb, E. A. Chernyshevb

a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
b M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation

Abstract: The primarily electrostatic nature of the intramolecular transannular SiN interaction was found from the electron-density distribution in crystalline 1-methylsilatrane at 100 K.

Language: English

DOI: 10.1070/MC2000v010n03ABEH001270



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