This article is cited in 10 papers

Homochiral and pseudoracemic 3,3- and 1,2-dimethyldiaziridine–silver nitrate complexes

R. G. Kostyanovsky^a, K. A. Lyssenko^b, V. R. Kostyanovsky<sup>a

a</sup> N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Diaziridine molecules in the title complexes 1 and 2, respectively, are bidentate ligands and form coordination polymers in which silver ions are coordinated to the trans-oriented nitrogen lone pairs of the ligands; complex 1 is homochiral (space group P2₁2₁2₁), whereas 2 is a pseudoracemate (space group Pbca) in which the alternation of ligands with opposite configurations is statistically disordered.

Language: English

DOI: 10.1070/MC2000v010n02ABEH001261

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