This article is cited in 7 papers

Communications

Application of NO₂/supercritical CO₂ system for safe and selective nitration of adamantanes and tertiary alkyl bromides

A. V. Budkova^ab, V. G. Merkulov^ab, R. E. Ivanov^a, M. N. Zharkov^a, I. V. Kuchurov^a, S. G. Zlotin<sup>a

a</sup> N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Abstract: A concise safe approach for selective nitration and nitroxylation of tert-alkanes, in particular adamantane, and tert-alkyl bromides utilizing NO₂ in supercritical CO₂ medium has been established. Major reaction products were tert-alkyl nitro compounds and tert-alkyl nitrates depending on the reaction conditions.

Keywords: nitroalkanes, nitrates, nitrogen dioxide, supercritical carbon dioxide, adamantane, tert-alkyl bromides.

Language: English

DOI: 10.1016/j.mencom.2023.06.006

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