M. I. Rybinskaya, A. A. Kamyshova, A. Z. Kreindlin, P. V. Petrovskii, “Generation of the metallonium cations [1,2-(CH2)2C5Me3OsC5Me5]2+, [1,1’-(CH2C5Me4)2Os]2+ and [1,2-(CH2)2C5Me3Os(1’-CH2C5Me4)]3+ in the CF3SO3H–O2 system”, Mendeleev Commun., 2001, Volume 11, Issue 4,Pages 137

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Generation of the metallonium cations [1,2-(CH₂)₂C₅Me₃OsC₅Me₅]²⁺, [1,1’-(CH₂C₅Me₄)₂Os]²⁺ and [1,2-(CH₂)₂C₅Me₃Os(1’-CH₂C₅Me₄)]³⁺ in the CF₃SO₃H–O₂ system

M. I. Rybinskaya, A. A. Kamyshova, A. Z. Kreindlin, P. V. Petrovskii

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The title dications and trication were generated from decamethylosmocene and [C₅Me₅OsC₅Me₄CH₂]⁺, respectively, by the interaction with dioxygen in CF₃SO₃H solutions.

Language: English

DOI: 10.1070/MC2001v011n04ABEH001456