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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2002 Volume 12, Issue 3, Pages 104–106 (Mi mendc4114)

This article is cited in 16 papers

Formation of cyclopropylazoarenes in the azo coupling reactions of the cyclopropanediazonium ion with active aromatic compounds

Yu. V. Tomilov, I. V. Kostyuchenko, E. V. Shulishov, O. M. Nefedov

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The decomposition of N-cyclopropyl-N-nitrosourea with K2CO3 generates a cyclopropyldiazonium intermediate, which is trapped in situ with 1- and 2-naphthols, 2,7-dihydroxynaphthalene or 8-hydroxyquinoline to afford azo coupling products.

Language: English

DOI: 10.1070/MC2002v012n03ABEH001595



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