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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2002 Volume 12, Issue 3, Pages 85–87 (Mi mendc4104)

This article is cited in 12 papers

3-Hydroxy-2,2-dimethylimidazolidin-4-one: the regioselective synthesis and chiral crystallization

I. V. Vystoropa, K. A. Lyssenkob, R. G. Kostyanovskyc

a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
c N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The condensation of glycine hydroxamic acid with acetone regioselectively leads to the formation of the title achiral cyclic hydroxamic acid, which crystallises from an acetone solution as chiral crystals (space group P212121) of (P,1R,3S) and (M,1S,3R) enantiomers.

Language: English

DOI: 10.1070/MC2002v012n03ABEH001603



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