Isokinetic relationship for nucleophilic substitution reactions with a participating thiosulfate ion in aqueous-organic media: a special reaction mechanism
Abstract:
For 72 nucleophilic substitution reactions at a saturated carbon atom with the participation of the S2O32− anion in aqueous-organic media, an isokinetic relationship with Tiso = 1130 K and l gkiso = 5.949 was found.