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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2002 Volume 12, Issue 1, Pages 40–41 (Mi mendc4082)

This article is cited in 4 papers

Isokinetic relationship for nucleophilic substitution reactions with a participating thiosulfate ion in aqueous-organic media: a special reaction mechanism

V. E. Bel'skii

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: For 72 nucleophilic substitution reactions at a saturated carbon atom with the participation of the S2O32 anion in aqueous-organic media, an isokinetic relationship with Tiso = 1130 K and l gkiso = 5.949 was found.

Language: English

DOI: 10.1070/MC2002v012n01ABEH001499



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