This article is cited in 1 paper

Dichlorosilane chlorination in the presence of propylene as an inhibitor at low pressures and 293 K

N. M. Rubtsov, G. I. Tsvetkov, V. I. Chernysh

A.G. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

Abstract: The strong inhibiting effect of C₃H₆ on the self-ignition of dichlorosilane–chlorine mixtures points to silylenes as chain carriers of the reaction. A critical concentration of chemically inert SF₆ (> 45%) drastically improves the inhibiting action of C₃H₆ indicating the occurrence of energy branching.

Language: English

DOI: 10.1070/MC2002v012n01ABEH001537

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